Chemical synthesis usually yields essentially the most thermodynamically steady ordered association, a precept additionally governing floor synthesis on an atomically degree two-dimensional (2D) floor, fostering the creation of structured 2D formations. The linear connection arising from energetically steady chemical bonding precludes the era of a 2D random community comprised of one-dimensional (1D) convoluted stripes by on-surface synthesis. Nonetheless, we underscored that on-surface synthesis possesses the aptitude not solely to style a 2D ordered linear community but additionally to manufacture a winding 2D community using a precursor with a mushy ring and intermediate state bonding inside the Ullmann response. Right here, on-surface synthesis was exhibited on Cu(111) using a 2D self-assembled monolayer array of 4,4′,5,5′-tetrabromodibenzo[18]crown-6 ether (BrCR) precursors. These precursors had been purposefully structured, with a crown ether ring on the core and Br atoms positioned on the head and tail ends, facilitating preferential connections alongside the elongated axis to foster a 1D stripe configuration. We illustrate how changes within the portions of the intermediate state, serving as a main linkage, can yield a labyrinthine, convoluted winding 2D community of stripes. The development of progress, underlying mechanisms, and digital constructions had been scrutinized utilizing an ultrahigh vacuum low-temperature scanning tunneling microscopy and spectroscopy (STM/STS) setup mixed with density practical idea (DFT) calculations. This experimental proof opens a novel performance in leveraging on-surface synthesis for the formation of a 2D random community. This discovery holds promise as a pioneering constituent within the development of a hoop host supramolecule, augmenting its functionality to ensnare visitor atoms, molecules, or ions.